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26 January 1994 Molecular constant error propagations into Franck-Condon integrals
A. V. Stolyarov, E. A. Pazyuk, I. V. Ushakov, R. S. Ferber
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Proceedings Volume 2205, 11th Symposium and School on High-Resolution Molecular Spectroscopy; (1994) https://doi.org/10.1117/12.166198
Event: High Resolution Molecular Spectroscopy: 11th Symposium and School, 1993, Moscow, Russian Federation
Abstract
An approximated analytical expression connecting the statistical uncertainties in rotational- vibration molecular constants with variations of Franck-Condon type integrals (FCI) has been obtained by applying a first order perturbation theory to the Morse oscillator model. The FCI dependencies on a presence of rotational-vibration interaction and effect of isotopic substitution have also been found in explicit forms.
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A. V. Stolyarov, E. A. Pazyuk, I. V. Ushakov, and R. S. Ferber "Molecular constant error propagations into Franck-Condon integrals", Proc. SPIE 2205, 11th Symposium and School on High-Resolution Molecular Spectroscopy, (26 January 1994); https://doi.org/10.1117/12.166198
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KEYWORDS
Oscillators
Statistical analysis
Statistical modeling
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