IR spectroscopy of interhalides XF3 and XF5 (X = Cl, Br)

Shavkat Sh. Nabiev

doi:10.1117/12.375372

25 January 2000 IR spectroscopy of interhalides XF₃ and XF₅ (X = Cl, Br)

Shavkat Sh. Nabiev

Proceedings Volume 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy; (2000) https://doi.org/10.1117/12.375372
Event: 13th Symposium and School on High-Resolution Molecular Spectroscopy, 1999, Tomsk, Russian Federation

Abstract

Interhalogens XF₃ and XF₅ (X equals Cl,Br) are widely used for reprocessing of nuclear materials, in electronic and iron-and-steel industries. At the same time XF₃ and XF₅ may be regarded among most dangerous components in the plumes of emergency ejections of these manufactures. The Cl and Br fluorides interact actively with atmospheric gases resulting in the formation of hydrogen halogen, Cl and Br oxyfluorides and oxides which are transformed into stable complexes (HHal)_x...(H₂O)_y, where Hal equals F, Cl, Br; x + y >= 2. A study into reaction mechanisms with a participation of the XF₃ and XF₅ compounds, their secondary compounds and the applicability of the remote laser control techniques requires comprehensive information on vibration spectra of interhalogens.

Citation Download Citation

Shavkat Sh. Nabiev "IR spectroscopy of interhalides XF₃ and XF₅ (X = Cl, Br)", Proc. SPIE 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy, (25 January 2000); https://doi.org/10.1117/12.375372

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