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IR absorption spectra of phosphosilicate glasses containing 2.5 and 9 mol.% of P2O5 were measured and analyzed. Quantum-chemical calculation of interaction of hydroxyl groups with the phosphorus centers was performed. The explanation of experimentally observed changes of shape and position of OH vibrational absorption bands was proposed.
Victor G. Plotnichenko,V. O. Sokolov,E. B. Kryukova, andEugeni M. Dianov
"Hydroxyl groups in high-purity glasses for fiber optics II: phosphosilicate glasses", Proc. SPIE 4083, Advances in Fiber Optics, (17 May 2000); https://doi.org/10.1117/12.385654
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Victor G. Plotnichenko, V. O. Sokolov, E. B. Kryukova, Eugeni M. Dianov, "Hydroxyl groups in high-purity glasses for fiber optics II: phosphosilicate glasses," Proc. SPIE 4083, Advances in Fiber Optics, (17 May 2000); https://doi.org/10.1117/12.385654