Microwave spectrum and structure of 2-methyl-1,3-dioxane

A. A. Shapkin; R. V. Galeev; L. N. Gunderova; M. G. Fayzullin; A. H. Mamleev

doi:10.1117/12.724780

12 December 2006 Microwave spectrum and structure of 2-methyl-1,3-dioxane

A. A. Shapkin, R. V. Galeev, L. N. Gunderova, M. G. Fayzullin, A. H. Mamleev

Proceedings Volume 6580, 15th Symposium on High-Resolution Molecular Spectroscopy; 658005 (2006) https://doi.org/10.1117/12.724780
Event: 15th Symposium on High-Resolution Molecular Spectroscopy, 2006, Nizhny Novgorod, Russian Federation

Abstract

The microwave rotational spectra of parent and five isotopic species with ¹³C and ¹⁸0 in natural abundance for 2- methyl-1,3-dioxane, C₅H₁₀0₂, have been observed in the 28.0 - 44.0 GHz frequency region. The a - and c - type transitions with 4 ≤ J ≤ 10 have been assigned. The rotational constants for all isotopomers were determined. The substituted coordinates of the heavy atoms were calculated from the principal moments of inertia of normal and ¹³C(2)¹²C₄H₁₀¹⁶0₂, ¹³C(4)¹²C₄H₁₀¹⁶0₂, ¹³C(5)¹²C₄H₁₀¹⁶0₂, ¹³C(7)¹²C₄H₁₀¹⁶0, C₅H₁₀¹⁶0¹⁸0 isotopomers using Kraitchman's equations. Partial substituted r_s structure of 2-methyl-1,3-dioxane molecule has been determined.

Citation Download Citation

A. A. Shapkin, R. V. Galeev, L. N. Gunderova, M. G. Fayzullin, and A. H. Mamleev "Microwave spectrum and structure of 2-methyl-1,3-dioxane", Proc. SPIE 6580, 15th Symposium on High-Resolution Molecular Spectroscopy, 658005 (12 December 2006); https://doi.org/10.1117/12.724780

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available