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12 December 2006 Quasiclassical description for rovibrational spectra of tetraatomics: the case of PH3
Borislav M. Kozlovskii, Sergei V. Petrov
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Proceedings Volume 6580, 15th Symposium on High-Resolution Molecular Spectroscopy; 65800C (2006) https://doi.org/10.1117/12.724898
Event: 15th Symposium on High-Resolution Molecular Spectroscopy, 2006, Nizhny Novgorod, Russian Federation
Abstract
Some new applications of so-called Rotational Energy Surface (RES) are discussed. As shown before, the method allows to discover some important qualitative features in rovibrational spectra of triatomics - e.g., energy level clustering. While trying to generalize the results, we developed a universal numerical procedure, allowing, particularly, to predict the formation of 6-fold energy clusters in spectra of PH3 by quasiclassical means.
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Borislav M. Kozlovskii and Sergei V. Petrov "Quasiclassical description for rovibrational spectra of tetraatomics: the case of PH3", Proc. SPIE 6580, 15th Symposium on High-Resolution Molecular Spectroscopy, 65800C (12 December 2006); https://doi.org/10.1117/12.724898
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KEYWORDS
Molecules
Chemistry
Erbium
Molecular spectroscopy
Tin
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