Presentation
5 October 2015 NIR and MIR charge transfer plasmons in wire-bridged antennas (Presentation Recording)
Author Affiliations +
Abstract
We investigate optical properties of wire-bridged plasmonic nanoantennas. Here we found two spectral features: a dipolar plasmon in the visible and a Charge Transfer Plasmon (CTP) in the infrared. The CTP depends sensitively on the conductance of the junction wire, offering a controllable way for tuning the plasmon resonance to the desired wavelength regime via junction geometries. Here we use single-particle dark field spectroscopy from UV, visible to IR to identify plasmonic modes in different spectrum regimes. The simulations using Finite-difference time-domain (FDTD) method are in good agreement with experiment: Increasing the junction wire width and concurrently the junction conductance blue shifts resonance positions, and simultaneously modifies scattering strengths, the linewidth of CTP and dipolar plasmon. We notice that CTP in a much longer wavelength regime and preserving a narrow line width, an important implication for designing IR plasmons with a high quality factor for enhanced spectroscopy and sensing applications. We also extend the CTP to the IR regime by increasing the wire length to create IR plasmon while keeping the line width of the resonance. Our work offers a way for studying the charge transfer properties in plasmonic nanostructures. Not only it adds another degree in understanding the charge transfer properties in plasmonic nanostructures but also offers an optical platform for studying molecules transport at optical frequencies and related applications.
Conference Presentation
© (2015) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Yue Zhang, Fangfang Wen, Samuel Gottheim, Nicholas S. King, Yu Zhang, Peter Nordlander, and Naomi J. Halas "NIR and MIR charge transfer plasmons in wire-bridged antennas (Presentation Recording)", Proc. SPIE 9547, Plasmonics: Metallic Nanostructures and Their Optical Properties XIII, 95470J (5 October 2015); https://doi.org/10.1117/12.2186474
Advertisement
Advertisement
KEYWORDS
Plasmons

Plasmonics

Nanostructures

Antennas

Finite-difference time-domain method

Infrared spectroscopy

Near infrared

Back to Top