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Were obtained a new nanocomposite (NC) based on poly N-epoxy prolyl carbazol (PEPC) and the coordination compound luminophore Eu(o-MBA)3Phen, where o-MBA is o- methylbenzoic acid and Phen – phenanthroline. Nanocrystals of Eu(o-MBA)3Phen with the dimensions ~ 50 nm were uniformly incorporated into the PEPC polymer matrix with various concentrations. The absorption spectra of coordination compounds and thin layers of NC PEPC/Eu(o-MBA)3Phen revealed 1 intensive absorption bands at 2.02 eV. Photoluminescence (PL) spectra showed an intense red luminescence at 578 – 699 nm, which is assigned to the transitions 4D0→7Fi (i= 0,1,2 3 4) in the 4f-shell of the Eu3+ ion.
Olga Bordian,Victor Verlan,Ion Culeac,Mihail Iovu, andVera Zubareva
"Technology and optical characterization of luminophore coordination compounds Eu(o-MBA)3Phen and NC PEPC/Eu(o-MBA)3Phen", Proc. SPIE 10010, Advanced Topics in Optoelectronics, Microelectronics, and Nanotechnologies VIII, 100101K (14 December 2016); https://doi.org/10.1117/12.2243058
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Olga Bordian, Victor Verlan, Ion Culeac, Mihail Iovu, Vera Zubareva, "Technology and optical characterization of luminophore coordination compounds Eu(o-MBA)3Phen and NC PEPC/Eu(o-MBA)3Phen," Proc. SPIE 10010, Advanced Topics in Optoelectronics, Microelectronics, and Nanotechnologies VIII, 100101K (14 December 2016); https://doi.org/10.1117/12.2243058