Anna Giardini Guidoni,1,2 Susanna Piccirillo,3 D. Scuderi,4 Mauro Satta,1,2 A. Filippi,4 D. Catone,4 A. Paladini,4 M. Speranza4
1Univ. degli Studi di Roma La Sapienza, CNR (Italy) 2Istituto Materiali Speciali-CNR (Italy) 3Univ. degli Studi di Roma Tor Vergata (Italy) 4Univ. degli Studi di Roma La Sapienza (Italy)
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Laser ablated chiral molecules and their clusters are studied by mass resolved R2PI technique. Attractive (electrostatic and polarization) and repulsive (steric) interaction influence both the shift and the binding energy of the complexes. In monofuctional systems, the homochiral complexes are found to be more stable than the heterochiral ones. The formation of stable L-Tyrosine-Aluminum (Al-Tyr) cluster in a supersonic beam expansion of a laser ablated Al-Tyr target has been observed.
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Anna Giardini Guidoni, Susanna Piccirillo, D. Scuderi, Mauro Satta, A. Filippi, D. Catone, A. Paladini, M. Speranza, "Laser studies of chiral molecules," Proc. SPIE 5121, Laser Processing of Advanced Materials and Laser Microtechnologies, (2 September 2003); https://doi.org/10.1117/12.513804