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The effects of the local dielectric environment on the surface-plasmon resonances of annealed gold-island films are studied experimentally and modeled theoretically. Gold- island films were annealed at 600 degree(s)C to produce spheroidal shape particles which exhibit well-resolved resonances in polarized, angle-resolved, absorption spectra. These resonances are shifted in different amounts by the depolarization effect of the surrounding medium (liquids with various refraction indices). Cross-section calculations based upon non-retarded, single-particle, dielectric interaction for these various configurations are presented and found to be in good agreement with the experimental observations.
Fabrice Meriaudeau,Todd R. Downey,A. Passian,Patrick Ian Oden,A. G. Wig,P. B. Crilly,S. Mangeant, andTrinidad L. Ferrell
"Thin metal island plasmon sensor", Proc. SPIE 3491, 1998 International Conference on Applications of Photonic Technology III: Closing the Gap between Theory, Development, and Applications, (4 December 1998); https://doi.org/10.1117/12.328749
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Fabrice Meriaudeau, Todd R. Downey, A. Passian, Patrick Ian Oden, A. G. Wig, P. B. Crilly, S. Mangeant, Trinidad L. Ferrell, "Thin metal island plasmon sensor," Proc. SPIE 3491, 1998 International Conference on Applications of Photonic Technology III: Closing the Gap between Theory, Development, and Applications, (4 December 1998); https://doi.org/10.1117/12.328749