Recently Cr4+-doped tunable laser crystals has become one kind of very important laser mediums. Cr4+ ions on a tetrahedral site is responsible for the near-infrared laser emission. It shows great promise as a very useful and practical laser crystal in many areas. It is also an important way to reach the tunable laser wavelength to 1.55 u which is the minimal dispersion region in optical fibers. In this paper we report some new development on Cr4+ doped tunable laser crystal which were finished in our lab. Cr4+ doped forsterite crystal is the first one in this area. By growing this crystal in oxygen atmosphere, considerable amount of Cr4+ occurs from the oxidation of Cr3+. A special technique had been adopted to protect the oxidation of Ir crucible. The second is Cr4+-doped YAG crystal, Ca2+ or Mg2+ codoped Cr:YAG host crystal has been grown in our lab, sized in 30 X 100 mm with excellent optical quality. We failed to produce Cr4+ in many host crystal, such as YAP, Al2O3 by oxidizing atmosphere or codoped with Ca2+, Mg2+.
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