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The high frequency absorption in crystalline and polycrystalline materials
arises mainly from sharp lattice vibrations, or due to the tail effect of the intense
lattice vibration absorption peak. In polycrystalline material there are also other
sources of absorption such as amorphous region continuum. A monatomic
material such as diamond or diamond like silicon has a simple cubic structure and
the lattice vibration absorption peak appears at a very high frequency (Infrared
frequency region 20,000 - 40,000 GHz). The 280 GHz region is then completely
free from the tail effect of lattice vibration absorption peak. If one can prepare a
specimen of such a material in which other millimeter wave absorption processes
are compensated, the window will have negligible absorption at 280 GHz.
Mohammed Nurul Afsar
"Window Materials for 280 GHz Continuous Wave Gyrotron", Proc. SPIE 1039, 13th Intl Conf on Infrared and Millimeter Waves, (18 November 1989); https://doi.org/10.1117/12.978770
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Mohammed Nurul Afsar, "Window materials for 280 GHz continuous wave gyrotron," Proc. SPIE 1039, 13th Intl Conf on Infrared and Millimeter Waves, (18 November 1989); https://doi.org/10.1117/12.978770