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We use ultrafast spectroscopy to resolve the interlayer charge scattering processes in heterostructures (HS) of two-dimensional materials. In a WSe2/MoSe2 HS we photogenerate intralayer excitons in MoSe2 and observe hole injection in WSe2 on the sub-picosecond timescale, leading to the formation of interlayer excitons. The temperature dependence of the build-up and decay of interlayer excitons provide insights into the coupling mechanisms. In a graphene/WS2 HS we observe ultrafast charge transfer from graphene to the semiconductor. The data are consistent with hot electron/hole transfer, whereby a tail the hot Fermi-Dirac carrier distribution in graphene tunnels through the Schottky barrier into WS2.
Stefano Dal Conte,Chiara Trovatello,Zilong Wang, andGiulio N. Cerullo
"Ultrafast charge transfer in heterostructures of 2D materials (Conference Presentation)", Proc. SPIE 11278, Ultrafast Phenomena and Nanophotonics XXIV, 112781B (10 March 2020); https://doi.org/10.1117/12.2544386
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Stefano Dal Conte, Chiara Trovatello, Zilong Wang, Giulio N. Cerullo, "Ultrafast charge transfer in heterostructures of 2D materials (Conference Presentation)," Proc. SPIE 11278, Ultrafast Phenomena and Nanophotonics XXIV, 112781B (10 March 2020); https://doi.org/10.1117/12.2544386