We investigated in situ the coupling spectra of a single gold nanorod and monolayer transition metal dichalcogenides (TMDCs) using nanomanipulation technique and single-particle spectroscopy. The resonant scattering peak of the hybrid redshifted, the full width at half maximum of the resonance narrowed, and the scattering intensity increased compared with those of the same nanorod on the glass surface, i.e., before coupling with monolayer TMDCs. Also, the spectral features varied with the distance between the nanorod and TMDCs, and the coupling interaction should be dominated mainly by the resonant energy transfer effect rather than the electron transfer process.
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