Band engineering of Sn and SnPb perovskite solar cells for efficiency enhancement

Gaurav Kapil; Muhammad Akmal Kamarudin; Kohei Nishimura; Daisuke Hirotani; Qing Shen; Satoshi Iikubo; Mengmeng Chen; Zhang Zheng; Shuzi Hayase

doi:10.1117/12.2594973

1 August 2021 Band engineering of Sn and SnPb perovskite solar cells for efficiency enhancement

Gaurav Kapil, Muhammad Akmal Kamarudin, Kohei Nishimura, Daisuke Hirotani, Qing Shen, Satoshi Iikubo, Mengmeng Chen, Zhang Zheng, Shuzi Hayase

Author Affiliations +

Proceedings Volume 11809, Organic, Hybrid, and Perovskite Photovoltaics XXII; 118090B (2021) https://doi.org/10.1117/12.2594973
Event: SPIE Organic Photonics + Electronics, 2021, San Diego, California, United States

Abstract

Recently, Sn perovskite solar cell (Sn PVK PV) are attracting attention. However, the efficiency was still lower than that of Pb perovskite solar cells. Recently, the Sn PVK PVs with efficiency higher than 10% have been reported from several research groups. The crystal defects include the presence of Sn4+, Sn2+ defect, I- defect, the presence of Sn0, the interstitial I- and so on. In order to decrease these defect densities, we have proposed some processes such as addition of Ge2+ ion, introduction of ethylammonium cation into A site, and surface passivation of perovskite grain boundary with diaminoethane dilute solution. Our results on efficiency enhancement (13%) is explained by the conduction and valence band energy level against carrier trap depth. In addition, an inverted SnPb perovskite solar cells with 23.3% efficiency is discussed from the view point of optimization of energy alignment.

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Citation Download Citation

Gaurav Kapil, Muhammad Akmal Kamarudin, Kohei Nishimura, Daisuke Hirotani, Qing Shen, Satoshi Iikubo, Mengmeng Chen, Zhang Zheng, and Shuzi Hayase "Band engineering of Sn and SnPb perovskite solar cells for efficiency enhancement", Proc. SPIE 11809, Organic, Hybrid, and Perovskite Photovoltaics XXII, 118090B (1 August 2021); https://doi.org/10.1117/12.2594973

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