Paper
2 November 2023 Identifying a laser ablation damage threshold for all-inorganic mixed-halide perovskite microwires
I. A. Matchenya, A. A. Marunchenko, N. A. Sizykh, A. V. Zenkevich, A. G. Nasibulin, A. P. Pushkarev
Author Affiliations +
Proceedings Volume 12920, XVI International Conference on Pulsed Lasers and Laser Applications; 1292006 (2023) https://doi.org/10.1117/12.3009477
Event: XVI International Conference on Pulsed Lasers and Laser Applications, 2023, Tomsk, Russian Federation
Abstract
All-inorganic mixed-halide perovskites are promising materials for a number of photonic and optoelectronic applications. Decent progress has been made in the field of the synthesis of their high-quality nano- and microcrystals exhibiting bright excitonic photoluminescence and laser generation tunable in a wide spectral range. However, the engineering of high-performance optoelectronic devices demonstrating long-term operational stability is challenging because of non-balanced charge carrier injection, Joule heating, and corrosion of metal electrodes. To balance charge carrier injection sandwich structures containing various electron- and hole-transport layers have been reported. To tackle the rest two issues utilization of a high thermal conductivity sapphire substrate as well as carbon electrodes could be the best choice. Herein, we employ 1030 nm fs laser source for the ablation of mixed-halide CsPb(Cl,Br)3 microwires grown on sapphire and covered with a single-walled carbon nanotube (SWCNT) thin film to produce planar microstructures of SWCNT/perovskite/SWCNT type. It is established, for CsPb(ClxBr1−x)3, the damage threshold value increases linearly with chlorine content in the crystal lattice and goes beyond one for cut SWCNT thin film (F0 = 0.68 J cm−2) when x ≥ 0.4. Thus, simple microdevices with tunable electroluminescence and spectral responsivity can be produced. We believe our findings will speed up progress in the development of a new platform for planar optoelectronics.
(2023) Published by SPIE. Downloading of the abstract is permitted for personal use only.
I. A. Matchenya, A. A. Marunchenko, N. A. Sizykh, A. V. Zenkevich, A. G. Nasibulin, and A. P. Pushkarev "Identifying a laser ablation damage threshold for all-inorganic mixed-halide perovskite microwires", Proc. SPIE 12920, XVI International Conference on Pulsed Lasers and Laser Applications, 1292006 (2 November 2023); https://doi.org/10.1117/12.3009477
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KEYWORDS
Laser ablation

Laser damage threshold

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