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Dye-doped porous silica microspheres can be prepared from liquid solution at temperatures near ambient. Microsphere diameter can be controlled between approximately 5.0 microns to in excess of a millimeter. The resulting microspheres can be attached to the distal end of an optical fiber in which the proximal end is attached to a spectrophotometer. Depending upon the organic species doped into the microsphere, a wide variety of sensing functions are possible. In this paper, the use of microsensors for measuring pH, temperature, and solvent content of aqueous solutions is demonstrated. Potential utility of this type of sensor to heavy metals detection and biomedical diagnostics is also discussed.
Edward J. A. Pope
"Fiber optic chemical microsensors employing optically active silica microspheres", Proc. SPIE 2388, Advances in Fluorescence Sensing Technology II, (8 May 1995); https://doi.org/10.1117/12.208484
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Edward J. A. Pope, "Fiber optic chemical microsensors employing optically active silica microspheres," Proc. SPIE 2388, Advances in Fluorescence Sensing Technology II, (8 May 1995); https://doi.org/10.1117/12.208484