Paper
4 May 2000 Temperature dependence of the C1+HN3 reaction from 300 to 480 K
Author Affiliations +
Abstract
The rate constant for Cl + HN3 over the temperature range 300-480 K has been studied in a flow reactor. Based on the rate of loss of HN3 and the rate of NCL(a1(Delta) ) generation, the temperature dependence of this reaction is described by the collision theory expression 1.2 +/- 0.3 X 10-11 T0.5 exp(-1514 +/- 93/T), with E0 equals 3.0 +/- 0.2 kcal mol-1 or an Arrhenius fit k(T) equals 2.0 +/- 1.0 X 10-10 exp(-1452 +/- 150/T) with Ea equals 2.9 +/- 0.2 kcal mol-1.
© (2000) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Gerald C. Manke II, Thomas L. Henshaw, Timothy J. Madden, and Gordon D. Hager "Temperature dependence of the C1+HN3 reaction from 300 to 480 K", Proc. SPIE 3931, Gas, Chemical, and Electrical Lasers and Intense Beam Control and Applications, (4 May 2000); https://doi.org/10.1117/12.384267
Advertisement
Advertisement
RIGHTS & PERMISSIONS
Get copyright permission  Get copyright permission on Copyright Marketplace
KEYWORDS
Chlorine

Molecules

Chemical species

Temperature metrology

Micro optical fluidics

Chemical lasers

Chemical oxygen iodine lasers

Back to Top