Paper
2 May 2000 Photo-oriented polymerization in hybrid glass waveguides
Kalaichelvi Saravanamuttu, Mark P. Andrews
Author Affiliations +
Abstract
The unique ways in which sol-gel derived silicate networks, that contain photosensitive methacrylate substituents, respond to light are described. Visible laser light in a hybrid acrylate-silica glass waveguide leads to photo initiated polymerization of the monomer. Polymerization proceeds with a high degree of spatial localization to create an 'optical fiber on a chip'. Photo transformations in the matrix are monitored by in situ waveguide Raman spectroscopy. Photo-orientation of the acrylate polymerization is controlled by the polarization sates of the guided wave. In this way, birefringence axes are reversibly written in the fiber.
© (2000) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Kalaichelvi Saravanamuttu and Mark P. Andrews "Photo-oriented polymerization in hybrid glass waveguides", Proc. SPIE 3943, Sol-Gel Optics V, (2 May 2000); https://doi.org/10.1117/12.384323
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KEYWORDS
Waveguides

Polymerization

Glasses

Polarization

Birefringence

Raman spectroscopy

Visible radiation

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