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The optical properties of as-grown and electron-irradiated α-Al203 (corundum) single crystals were investigated at low
temperatures, using vacuum-W (VUV) time-resolved luminescence spectroscopy under the synchrotron radiation
excitation. It has been shown that in the electron-irradiated crystals the excitation of self-shrunk exciton emission extends
to the region of interband transitions. The decay time of the 7.6-eV emission of the self-shrunk excitons in as-grown
crystals was found to be about 7 and 23.8 ns respectively for the excitations in the excitonic band and at energies at
which several electron-hole pairs are generated. In the irradiated crystals, these lifetimes were by about 2 ns longer than
in the as-grown ones. For both crystal states, the nature and dynamics of the electronic excitations are discussed.
Marco Kirm,Vachagan Harutunyan,Vladimir Makhov, andSebastian Vielhauer
"VUV luminescence of as-grown and electron irradiated corundum single crystals", Proc. SPIE 5946, Optical Materials and Applications, 594606 (12 June 2006); https://doi.org/10.1117/12.639064
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Marco Kirm, Vachagan Harutunyan, Vladimir Makhov, Sebastian Vielhauer, "VUV luminescence of as-grown and electron irradiated corundum single crystals," Proc. SPIE 5946, Optical Materials and Applications, 594606 (12 June 2006); https://doi.org/10.1117/12.639064