Paper
1 September 2010 Light trapping effect from randomized textures of Ag/ZnO back reflector on hydrogenated amorphous and nanocrystalline silicon based solar cells
Baojie Yan, Guozhen Yue, Laura Sivec, Jessica M. Owens, Ken Lord, Jeffrey Yang, Subhendu Guha, Chun-Sheng Jiang
Author Affiliations +
Abstract
We report our progress in the optimization of Ag/ZnO back reflectors (BR) for a-Si:H and nc-Si:H solar cells. Theoretically, a BR with a smooth metal surface and a textured dielectric surface would be more desirable. A smooth metal/dielectric interface reduces the plasmonic resonance loss and parasitic losses due to light trapped in sharp angles; a textured dielectric/semiconductor interface provides scattering for light trapping. In order to obtain sufficient light scattering at the ZnO/silicon interface, a highly textured ZnO layer is normally used. However, a highly textured ZnO surface causes deterioration of nc-Si:H material quality. In addition, to make a highly textured ZnO surface, a thick ZnO layer is needed, which could introduce additional absorption in the bulk ZnO layer and reduce the photocurrent density. Therefore, Ag/ZnO BR structures for nc-Si:H solar cells needs to be optimized experimentally. In this study, we found that an optimized Ag/ZnO BR for nc-Si:H solar cells is constructed with textured Ag and thin ZnO layers. Although a textured Ag layer might cause certain losses resulting from plasmonic absorption, the enhanced light scattering by a moderately textured Ag layer makes it possible to use a thin ZnO layer, where the absorption in the ZnO layer is low. With such a BR, we achieved a short-circuit current density of over 29 mA/cm2 from a nc-Si:H single-junction solar cell. Using the high performance nc-Si:H cell in an a-Si:H/nc- Si:H/nc-Si:H triple-junction structure, we achieved an initial active-area efficiency of 14.5% with a total current density exceeding 30 mA/cm2.
© (2010) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Baojie Yan, Guozhen Yue, Laura Sivec, Jessica M. Owens, Ken Lord, Jeffrey Yang, Subhendu Guha, and Chun-Sheng Jiang "Light trapping effect from randomized textures of Ag/ZnO back reflector on hydrogenated amorphous and nanocrystalline silicon based solar cells", Proc. SPIE 7771, Thin Film Solar Technology II, 777102 (1 September 2010); https://doi.org/10.1117/12.859867
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Cited by 5 scholarly publications and 27 patents.
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KEYWORDS
Zinc oxide

Solar cells

Silver

Light scattering

Interfaces

Bromine

Absorption

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