We have investigated ablation process of silica glass induced by X-ray irradiation. X-rays around 100 eV were
generated by irradiation of Ta targets with Nd:YAG laser light. The laser plasma soft X-rays have a pulse
duration of 10 ns. The soft X-rays were focused on silica surfaces at up to 108 W/cm2. We found that silica glass
can be ablated by X-ray irradiation. Typically, the ablated surface have a roughness of 1 nm after ablation by
500 nm in depth. Further, trenches with a width of 50 nm can be clearly fabricated on silica surface. Thus, high
quality, practical micromachining can be achieved by the X-ray technique. It is remarkable that more precise
features can be fabricated on silica surface than the thermal diffusion length. The results implies non-thermal
ablation process. We observed ions ejected from silica surfaces during the irradiation and found that ions are
almost atomic species such as Si+, O+, Si2+, O2+, SiO+. The results revealed that silica surfaces are broken into atomic species by X-ray irradiation. Among X-ray ablated species, 0.5-15 % are estimated to be ionized. Even though 0.5 % atoms are ionized in silica surface, the energy density of Coulomb repulsive force is higher
than the energy density of binding energy of silica glass. Therefore, we can conclude that Coulomb repulsion
between X-ray generated ions are essential for X-ray ablation of silica glass.
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