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Perovskite light-emitting diodes (PeLEDs) are considered as a promising candidate for next-generation solution-processed full-color displays. However, the external quantum efficiency as well as the operational stability of deep-blue (< 460 nm) PeLEDs still lag far behind compared to their red and green counterparts. Herein, the rapid crystallization method based on antisolvent bathing is proposed for trealization deep-blue PeLEDs. By promoting the immediate removal of precursor solvents from the wet perovskite films, the development of the quasi-2D Ruddlesden‒Popper perovskite (2D-RPP) crystals with n value of < 3 was completely hampered, so that phase-pure 2D-RPP films whose bandgap is suitable for deep-blue PeLEDs were successfully obtained.
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