21 September 2015 Creation of guiding patterns for directed self-assembly of block copolymers by resistless direct e-beam exposure
Author Affiliations +
Funded by: European Union’s Seventh Framework Programme, European Research Council, European Community's Seventh Framework Programme, European Community’s Seventh Framework Programme, European Union Seventh Framework Programme, European Union Seventh Framework Program, EC and Spanish Ministry, Seventh Framework Programme (EC Seventh Framework Programme), European Nanoelectronics Initiative Advisory Council (ENIAC), MECD
Abstract
We present an approach for the creation of guiding patterns to direct the self-assembly of block copolymers. A neutral layer of a brush polymer is directly exposed by electrons, causing the cross-linking of the brush molecules, and thus changing its local affinity. The advantage relies on the achievable resolution and the reduction of the process steps in comparison with deep UV and conventional electron beam lithography, since it avoids the use of a resist. We envision that this method will be highly valuable for the investigation of high-chi directed self-assembly materials and complex guiding pattern designs, where pattern placement and resolution are becoming critical.
© 2015 Society of Photo-Optical Instrumentation Engineers (SPIE) 1932-5150/2015/$25.00 © 2015 SPIE
Laura Evangelio, Marta Fernández-Regúlez, Xavier Borrisé, Matteo Lorenzoni, Jordi Fraxedas, and Francesc Pérez-Murano "Creation of guiding patterns for directed self-assembly of block copolymers by resistless direct e-beam exposure," Journal of Micro/Nanolithography, MEMS, and MOEMS 14(3), 033511 (21 September 2015). https://doi.org/10.1117/1.JMM.14.3.033511
Published: 21 September 2015
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CITATIONS
Cited by 7 scholarly publications and 2 patents.
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KEYWORDS
Directed self assembly

Polymers

Electron beam lithography

Atomic force microscopy

Silicon

Annealing

Deep ultraviolet

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