A new light-responsive arylazopyrazole (AAP) containing a polymer matrix thin film is fabricated by spin-coating different concentrations of the AAP azo dye into the polydimethylsiloxane (PDMS) polymer at 150°C. The new AAP molecular switch was also used to fabricate a solid-state PDMS-AAP waveguide by contact lithography and soft replica modeling methods in the micrometer scale. The refractive index of the spin-coated photoswitchable material can be modulated via the reversible trans-to-cis photoisomerization behavior of the AAP unit using different concentrations. When 0.01 M solution of the AAP unit was used, the refractive of the composite was 2.32 in the trans state and dropped to 1.85 in the cis state in the operating wavelength of 340 nm. At higher concentrations of 0.020 and 0.03 M, a wide refractive index tuning is achieved under the same wavelength. In 0.030 M, the refractive index was 2.65 for the trans state and 2.0 for the cis state. The results suggest that the increase in refractive index tuning is related to the concentration of the AAP unit of the composite film. Theoretically, the spectral properties of the composite film are also simulated with two methods: (1) the Maxwell equations and (2) the frequency dependent finite element, showing excellent agreement for the different propagation modes of the proposed waveguide for regulated signals of 365/525 nm wavelengths. Furthermore, the photoisomerization of the PDMS-AAP thin film is analyzed with UV–vis spectroscopy to demonstrate the isomerization responses of the AAP moiety in the solid state. In addition, preliminary photomechanical actuation properties of the composite film have been investigated. The PDMS-AAP waveguide described provides a new approach for optically tunable photonics applications in the UV–visible region.
A new light responsive arylazopyrazole (AAP) containing polymer matrix thin film is fabricated by spincoating of different concentrations of the AAP azo dye into the polydimethylsiloxane (PDMS) polymer at 150°C. The new AAP molecular switch was also used to fabricate a solid-state PDMS-AAP waveguide by contact lithography and soft replica modeling methods in the micrometer scale. The refractive index of the spin-coated photoswitchable material can be modulated via the reversible trans-to-cis photoisomerization behavior of the AAP unit using different concentrations. When 0.01 M solution of the AAP unit was used, the refractive of the composite was 2.32 in the trans state and dropped to 1.85 in the cis state in the operating wavelength of 340 nm. At higher concentrations of 0.020 and 0.03 M, a wide refractive index tuning is achieved under the same wavelength. In 0.030 M the refractive index was 2.65 for the trans state and 2.0 for the cis state. The results suggest that the increase in refractive index tuning is related to the concentration of the AAP unit of the composite film. Theoretically, the spectral properties of the composite film are also simulated with two methods: 1) the Maxwell Equations; and 2) the frequency dependent finite element, showing excellent agreement for the different propagation modes of the proposed waveguide for regulated signals of 365/525 nm wavelengths. Furthermore, the photoisomerization of the PDMS-AAP thin film is analyzed with UV-vis spectroscopy to demonstrate the isomerization responses of the AAP moiety in the solid state. Additionally, preliminary photomechanical actuation properties of the composite film have been investigated. The PDMS-AAP waveguide described in this study provides a new approach for optically tunable photonics applications in the Visible-IR region.
Hyperbolic Metamaterials, as a non-magnetic anisotropic artificial structure, show metal properties in one direction and dielectric behavior in orthogonal directions. The proposed hyperbolic metamaterial filter in this project is designed with the metal wire mesh perpendicular to the alternative layers of dielectric materials, keeps TM center wavelength unchanged for the different angle of incident light in MDIR regime. The geometric size of this nanostructure is smaller than the working wavelength and supports big wavevectors due to hyperbolic dispersion. In contrast with conventional Bragg stack, the copper fakir bed makes the transmission properties of the filter the same. For this purpose, the state-of-the-art fabrication methods are required to make such small dimensions in alternative layers of amorphous silicon and silicon dioxide. In this work, first we demonstrate the simulation of Bragg stack with RCWA and finite element methods. Then we focus on our first-time multistep lithography method used to fabricate the filter at Cornell University’s Nanoscale Science and Technology Center. Finally, we experimentally verify the optical characteristic of the fabricated filter using Fourier-transform infrared spectroscopy. The experimental and spectrometry data shows that transmission properties of the hyperbolic metamaterial filter remain the same for oblique TM polarized incident light.
Tunable dielectric meta-surface nanostructures offer incredible performance in optical application due to their extraordinary tunability of the polarization and engineering the dispersion of light with low loss in infrared range. In this article, we designed and experimentally measured the tunability of all-dielectric subwavelength silicon nanoparticles with the help of the temperature-based refractive index of the liquid crystal in the telecom regime. The proposed structure composed of high dielectric nanodisk surrounded by nematic liquid crystal (NLC) is simulated with numerical software, assembled with pre-alignment material, and optically measured by Fourier-transform infrared (FTIR) spectroscopy. The simulated result is compatible with the practical measurements, shows that the tunability of 30nm is achieved. Electric and magnetic resonance modes of the high dielectric nanodisks are tailored in different rates by anisotropic temperature dependent NLC. The phase switching of anisotropic to isotropic nematic liquid crystal enables spectral tunning of the two modes of all dielectric metasurface and modifies the symmetry of the optical response of the metamaterial structure.
Vanadium dioxide (VO2) as a phase-change material controls the transferred heat during phase transition process between metal and insulator states. At temperature above 68°C, the rutile structure VO2 keeps the heat out and increases the IR radiation reflectivity, while at the lower temperature the monoclinic structure VO2 acts as the transparent material and increase the transmission radiation. In this paper, we first present the metal-insulator phase transition (MIT) of the VO2 in high and low temperatures. Then we simulate the meta-surface VO2 of metamaterial reflector by Ansys HFSS to show the emittance tunability (Δε) of the rutile and monoclinic phase of the VO2. In next section, we will review the recent progress in the deposition of thermochromic VO2 on glass and silicon substrate with modifying the pressure of sputtering gases and temperature of the substrate. Finally, we present the results of the in-situ sputtered VOx thin film on thick SiO2 substrate in different combination of oxygen and argon environment by V2O5 target at temperature higher than 300°C and then, analyze it with x-ray diffraction (XRD) method. The thermochromic VO2 based metamaterial structures open a new route to the passive energy-efficient optical solar reflector in the past few years.
In this project we design and fabricate a hyperbolic metamaterials-based narrowband notch filter for the mid-wave infrared regime with an angle-of-incidence independent center-wavelength for TM polarized incident light. To achieve angle of incidence independence, a subwavelength sized array of copper wires is inserted in a vertical orientation and permeates the three middle layers of the seven layer Bragg stack filter. Analysis using Maxwell- Garnett theory and full-wave electromagnetic modeling, and the fabrication progress to date are presented. Narrowband notch filters have applications in optical communications systems, and remote sensors such as hyperspectral and multi-spectral sensing and imaging.
In this project we propose and fabricate a hyperbolic metamaterials-based narrowband notch filter for the infrared regime with a center wavelength that remains fixed as the angle of incidence changes from 0 to 30 degrees for TM polarization. This novel device modifies a conventional Bragg reflector by including a middle resonance layer that opens up a narrow, highly transmissive band. To achieve angular independence, a subwavelength sized array of silver wires are inserted in a vertical orientation and permeate all 7 Si and SiO2 layers of the structure.
In this work the theoretical underpinnings are explored using Maxwell-Garnett Theory, and simulated with 3D finite element full wave electromagnetic modeling software. Simulations demonstrate that the device is capable of up to 60% transmission at a fixed center wavelength for TM polarization in the infrared.
The device is fabricated using typical microfabrication techniques. The silver nanowires are fabricated via DC electrodeposition. The angle and polarization dependent transmission, reflection and absorption of the device are experimentally measured, and scanning electron microscopy images of the structure are shown.
Though the experimental validation of this device is performed for the infrared regime, scaling the structural sizes can extend the operating regime to higher and lower wavelengths. Whether used as a stand-alone filter, or integrated into a hyperspectral array, the angle-independent response of this filter has many uses in remote sensing applications.
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