In this work, we dope Mn2+ ions into an organic-inorganic hybrid quasi-bulk 3D perovskite with the addition of tris(4-fluorophenyl)phosphine oxide (TFPPO) dissolved in a chloroform antisolvent to achieve green perovskite LEDs (PeLEDs) with a 14.0% EQE and a 128,000 cd/m2 peak luminance. While TFPPO dramatically increases the PeLEDs’ EQE, the operational stability is compromised. At 5mA/cm2, our PeLED fabricated with a pure chloroform antisolvent (EQE=2.97%) decays to half of its maximum luminance in 37.0 minutes. Alternatively, our PeLED fabricated with TFPPO (EQE=14.0%) decays in 2.54 minutes. Consequently, we studied both photophysical and optoelectronic characteristics before and after PeLED electrical degradation.
Metal halide perovskites (MHPs) have established their prominence in the field of optoelectronics, exhibiting considerable potential for use in light-emitting diodes (LEDs) spanning the red, green, blue, and even near-infrared spectra. Despite this, the exploration of MHPs within the ultraviolet light emission domain remains comparatively underexplored. In this study, we exploit the inherent versatility of perovskite composition and dimensionality to address this research gap. By integrating long organic ligands and mixed halides, we fabricate two-dimensional (2D) MHP thin films capable of achieving a diverse range of bandgaps within the ultraviolet region. To enhance the coverage of these thin films, we introduce water-based additives and a two-step annealing process into the fabrication protocol. A variety of analytical techniques, including absorption and photoluminescence spectra analysis, along with atomic force microscopy, were employed to characterize these 2D perovskite thin films. Our findings underscore the vast potential of MHPs for ultraviolet light-emitting diodes. This work is aimed at inspiring further investigations in this promising yet under-studied domain, paving the way for novel advancements in realization of bright and efficient ultraviolet emitting technology.
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