Fundamental electron dynamics at the attosecond frontier and their direct coupling to structural dynamics of matter yield novel insights into the energy-distribution and protection mechanisms of Nature. The angular-streaking technique has exclusively demonstrated its capability of obtaining the full time-energy structure of XFEL pulses with attosecond resolution directly in the time-domain, thus enabling XFELs to study electron dynamics from element-specific vistas and their importance as onset of subsequent structural dynamics. We will present latest advances of this technique together with first results from the 2022 EuXFEL atto-campaign and the complementary prospects of the FLASH 2020+ innovation project at DESY.
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