The method of laser-induced metal deposition from solution was applied in the continuous in situ laser generation of metal copper catalysts for model organic synthesis reactions. The gas phase products producing during laser-induced copper deposition were analyzed by mass spectrometry whereas solutions used for the copper deposition were investigated before and after laser irradiation using chromato-mass spectrometry and NMR spectroscopy. It was found out that the catalysis of the studied organic reactions by metal catalysts generated during laser deposition process occurs only upon laser irradiation of the reaction mixture.
The study showed that organic alcohols with 1,2,3,5,6 hydroxyl groups can be used as reducing agents for laser-induced
copper deposition from solutions (LCLD).Multiatomic alcohols, sorbitol, xylitol, and glycerol, are shown to be effective
reducing agents for performing LCLD at glass-ceramic surfaces. High-conductivity copper tracks with good topology
were synthesized.
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