It is crucial to obtain infrared emission coating materials with emissivity close to one unit for remote sensing temperature measurement, earth climate monitoring and other fields. In order to obtain large-area uniform high emissivity coating, multi-layer spraying and multi-walled carbon nanotubes doping were used to enhance the emissivity of commercial black paint NVC811-21 from 8μm to 14μm. Compared with the coating directly sprayed with NVC811-21, the emissivity of the coating in the normal band from 8μm to 14μm in the atmosphere can be increased from 0.965 to 0.978. In addition, from the spectral emissivity of the coating in this band, the doping of carbon nanotubes can improve the emissivity near 10μm of the coating. For NVC811-21, this improves the uniformity of the spectral emissivity of the coating material. Due to the application of NVC811-21 in the actual service of the on-orbit blackbody, this paper's preparation method may help improve the emissivity of the on-orbit blackbody and the measurement accuracy of satellite remote sensors.
Radiation temperature measurement is a non-contact temperature measurement, which has important applications in quantitative remote sensing, industrial thermal monitoring, biomedical engineering and military field. The infrared radiation of an object is directly proportional to its emissivity, which is an important parameter that affects radiation temperature measurement. In order to obtain the spectral emissivity of an object, this paper proposes a method for measuring spectral emissivity based on the radiation at multiple temperatures. Based on Planck's law of radiation, the expression of spectral emissivity is theoretically given by deriving the relationship between spectral emissivity, contact temperature and radiation. The simulation is carried out based on theoretical derivation. The spectral emissivity of three samples is simulated. The waveband of the samples is 8-14μm, and the spectral emissivity does not change with temperature. Two algorithms are used to avoid the problem of singular values in direct calculation. Based on the constrained linear least-squares method, the average relative errors of the three samples are 7.0%, 7.2%, and 6.2%. The maximum relative errors are 22.1%, 18.9% and 15.0%. Based on the improved constrained linear least-squares method, the average relative errors of the three samples are 2.2%, 1.1%, and 3.0%, and the maximum relative errors are 6.7%, 3.2%, and 4.2%. The simulation results verify the feasibility of inversion of spectral emissivity at multiple temperatures. The results show that the improved constrained linear least-squares method has smaller average relative errors.
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